Description
Nano-sized molecular rings, best known as Nanorings, are currently the subject of intense research efforts motivated by to their outstanding photochemical, electrochemical and chemical properties. The rare examples of e rich nanorings described so far in literature are built from carbazoles,phenylenes,or porphyrinunits
The aim of this project is to develop a method to access a new class of water-soluble, e deficient, cationic conjugated organic macrocycles of diameters ≥ 2 nm. Due to their large size and conjugated character, such structures are expected to show outstanding chemical and physical properties finding applications in many different fields like molecular electronics, sensing, or imaging. The integration of e—deficient AND cationic subunits in conjugated nanorings is expected to afford a new class of compounds with unprecedented propertiesdue to their high e accepting character, rigidity, circular shape, electron delocalization and water-solubility. The objective of this work will be to synthesize nanorings incorporating 4,4‑bipyridinium subunits (also known as viologens). These species have been selected for their e deficient nature, synthetic availability, well defined redox properties and structural tunability. These dicationic units have already proved extremely useful for the development of organic batteries, photo / electrochromic devices, molecular machines, or as electron mediators in catalysis. However, organizing viologens into nanorings is not trivial and the metal template approach used for the preparation of porphyrin nanorings3 is not applicable to viologens. We will explore in this project an original and straightforward strategy to address these issues and provide access to water-soluble cationic conjugated nanorings based on viologens . This project will be developed as part of an ongoing collaboration between the chemistry lab. at ENS de lyon and ICR at Aix-Marseille University (D. Bardelang and A Kermagoret).The internship will be funded by ANR (ANR Stargate -27)
Profile
Most of the experimental work will focus on the synthesis and characterization of novel organic building blocks required for the synthesis of the targeted rings. The applicant will thus ideally have a multidisciplinary background with good expertise in (or taste for) organic chemistry.
Starting date
02-20
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